Halomethane Totally Explained

Everything about Halomethane totally explained

Halomethane compounds are molecules of methane (C H₄) with one or more of the hydrogen atoms replaced with halogen atoms. The halogens are found in group 17 of the periodic table of the elements. Forming covalent bonds, these compounds are generally stable.

Environmental aspects

While these are all considered to be human-made compounds, they may appear inadvertently via natural processes in the environment through the introduction of other non-natural industrial materials. An example is the creation of carbon tetrachloride in small (yet slightly dangerous) quantities when carbon bearing materials are present in drinking water disinfected with chlorine gas. As carbon tetrachloride is believed to be carcinogenic (cancer causing), chlorine gas is being replaced with chloramine for this use.
Some of these compounds, while normally inert, become active when exposed to ultraviolet light found at high altitudes and can destroy the earth's protective ozone layer. The most damaging ones are being phased out of use as industrial materials.

Chemical properties

While most of these compounds are considered inert under normal conditions, some are irritants. At high temperatures there may be toxic byproducts produced.

Uses

Combinations of halogens with short carbon chains form related compounds such as haloethanes, halopropanes, halobutalines, etc, typically useful as refrigerants, fire suppressing gases, solvents, and as starting points for stable and useful plastics such as Teflon. Some are in crystal form. Freon is a trade name for a group of chlorofluorocarbons used primarily as refrigerants. The word Freon is a registered trademark belonging to E.I. du Pont de Nemours & Company.

Listing of common halomethanes

The naturally occurring halogen elements forming halomethanes are:

Fluorine, being the most active element forms extremely stable compounds with carbon.
- Fluoromethane (methyl fluoride, CH₃F) is used in semiconductor manufacture. Known as Freon-41.
- Difluoromethane (CH₂F₂) is a refrigerant with zero ozone depletion potential
- Trifluoromethane (fluoroform, CHF₃) is used in the semiconductor industry and as a refrigerator. Also known as Freon-23.
- Carbon tetrafluoride (CF₄), a low boiling point gas used in refrigeration. Known as Freon-14, refrigerant 14, R14 and other names

Chlorine

Chloromethane (methyl chloride, CH₃Cl) was used as a refrigerant, now is used as an intermediate in the production of silicone polymers and in synthesis as a methylation and chloration agent. Also known as Freon 40.
Dichloromethane (DCM, methylene chloride, CH₂Cl₂) is a widely used organic solvent mainly used as a solvent for industrial processes, stripping paint, and degreasing parts. However, it has other uses as varied as decaffeinating coffee and preparing flavor extracts.
Chloroform (trichloromethane, CHCl₃) used to be used as an anesthetic but fell out of use due to its toxicity. It finds use today as an industrial solvent and in the production of dyes and pesticides.
Carbon tetrachloride (CCl₄) binds four chlorine to each carbon, forming a non-flammable liquid of low boiling point. Once used as a cleaning fluid and in fire extinguishers, it's now known to be extremely toxic and carcinogenic.

Bromine

Bromomethane (methyl bromide, CH₃Br) was formerly used as a soil sterilant and fumigant. It strongly depletes ozone layer.
Dibromomethane (methylene bromide, CH₂Br₂) is a solvent and it's also used in organic synthesis.
Bromoform (CHBr₃) used as solvent and flame retardant. Now mainly used as a chemical reagent and for separation of heavy minerals.
Carbon tetrabromide (CBr₄)

Iodine

Iodomethane (methyl iodide, CH₃I) is a reagent for S_N2 substitution reactions and a methylation agent.
Diiodomethane (CH₂I₂) used as a solvent and for separation of heavy minerals like bromoform.
Iodoform (CHI₃) is a former antiseptic.
Carbon tetraiodide (tetraiodomethane, CI₄) is used as an iodination agent.

Combinations - substitutions of fluorine, chlorine and bromine for the hydrogens yields various refrigerant or fire suppressing gases.

Chlorofluoromethane (CH₂ClF), Freon-31 is a refrigerant.
Bromofluoromethane (CH₂BrF) is used in organic synthesis.
Fluoroiodomethane (CH₂FI)
Bromochloromethane (CH₂BrCl), Halon 1011 was used in fire extinguishers.
Chloroiodomethane (CH₂ClI)
Bromoiodomethane (CH₂BrI)
Chlorodifluoromethane (CHClF₂), Freon-22
Dichlorofluoromethane (CHCl₂F), Freon-21
Chlorotrifluoromethane (CClF₃), Freon-13
Trichlorofluoromethane (CCl₃F), Freon-11
Dibromodifluoromethane (CBr₂F₂)
Dichlorodifluoromethane (CCl₂F₂), Freon-12
Dibromodifluoromethane (CBr₂F₂)
Bromochlorodifluoromethane (CBrClF₂)

Further Information

Get more info on 'Halomethane'.

External Link Exchanges

Do you know how hard it is to get a link from a large encyclopaedia? Well we're different and will prove it. To get a link from us just add the following HTML to your site on a relevant page:

<a href="http://halomethane.totallyexplained.com">Halomethane Totally Explained</a>

Then simply click through this link from your web page. Our crawlers will verify your link, extract the title of your web page and instantly add a link back to it. If you like you can remove the words Totally Explained and embed the link in article text.
As long as your link remains in place, we'll keep our link to you right here. Please play fair - our crawlers are watching. Your site must be closely related to this one's topic. Any kind of spamming, dubious practises or removing the link will result in your link from us being dropped and, potentially, your whole site being banned.